Код:
function RenameFile(const OldName, NewName: string): Boolean;
begin
{$IFDEF MSWINDOWS}
Result := MoveFile(PChar(OldName), PChar(NewName));
{$ENDIF}
{$IFDEF LINUX}
Result := __rename(PChar(OldName), PChar(NewName)) = 0;
{$ENDIF}
end;
Пользуй MoveFile. Описалово в MSDN.